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AWWA JAW30301

M00001900

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AWWA JAW30301 Journal AWWA - THM Formation by the Transfer of Active Chlorine From Monochloramine to Phloroacetophenone

Journal Article by American Water Works Association, 05/01/1991

Topudurti, Kirankumar V.;Haas, Charles N.

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The purpose of this study was to investigate whether there is a direct transfer of active chlorine (Cl+) from monochloramine to phloroacetophenone (PAP), leading to the formation of trihalomethanes. The reactions of monochloramine and free chlorine with PAP were studied in batch and flow-through reactors. Chloroform was found to be formed at neutral pH, primarily as a result of direct transfer of Cl+ from monochloramine to PAP. Although the chloroform concentration was two orders of magnitude less with monochloramine than with free chlorine, monochloramine can still produce significant concentrations of chloroform. Includes 14 references, tables, figures.

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